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Maymann, who previously headed AOL International, will report to Arianna Huffington, president and editor-in-chief, as well as chair of the Huffington Post Media Group, the company said.
Maymann joined AOL Inc after the company bought goviral.com, which Maymann had co-founded, for $96.7 million in January 2011.
The Huffington Post, founded in 2005, was bought by AOL in 2011 for $315 million.
(Reporting By Nicola Leske; Editing by Gerald E. McCormick)